You can run a server task to match applications between the inventory that is populated with system applications in ePO - On-prem and the CPE dictionary.
Inventory is pulled from the endpoints using ePO - On-prem.
The CPE dictionary is imported.
On the ePO - On-prem console, select Menu → Automation → Server Task.
Click New task, enter a name for the task, then click Next.
From Actions, select Solidcore: CPE Matching inventory applications with the latest imported CPE Dictionary and click Next.
Schedule the task and click Next.
Save the server task.